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Updated: Nov 29, 2025

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[8]-2,6-氨酸氧化物的光组合

Evan E Hurlow1, Janice B Lin1, Morris J Dweck1

  • 1Department of Chemistry and Biochemistry, University of California-Los Angeles, 607 Charles E. Young Drive East, Los Angeles, California 90095-1569, United States.

Journal of the American Chemical Society
|November 23, 2020
PubMed
概括

研究了pyridinophane N-oxides的光化学反应. 一个统一的机制解释了竞争的过程,得到了新的异环发现和DFT计算的支持.

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The Cope rearrangement is classified as a [3,3] sigmatropic shift in 1,5-dienes, leading to a more stable, isomeric 1,5-diene. The reaction involves a concerted movement of six electrons, four from two π bonds and two from a σ bond, via an energetically favorable chair-like transition state.
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