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Updated: Nov 28, 2025

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides
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Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides

Published on: May 26, 2019

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种族性三级C-H债券的enantio-convergent氨基化

Kai Lang1, Chaoqun Li2, Isaac Kim1

  • 1Department of Chemistry, Merkert Chemistry Center, Boston College, Chestnut Hill, Massachusetts 02467, United States.

Journal of the American Chemical Society
|November 30, 2020
PubMed
概括

这项研究引入了一种新型的催化方法,使用来使 Racemic 三级 C-H 键 enantioconverge,从而产生带有四级立体中心的奇拉分子. 这种脱血功能推进了立体选择性合成.

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