肌肉模拟协同共价和超分子聚合物:光触发形成导致机械性能提升
Zhaoming Zhang1, Lin Cheng1, Jun Zhao1
1School of Chemistry and Chemical Engineering, Frontiers Science Center for Transformative Molecules, Shanghai Jiao Tong University, Shanghai 200240, PR China.
Journal of the American Chemical Society
|November 30, 2020
概括
研究人员使用协同共价和超分子聚合物 (CSP) 模拟肌肉收缩. 光辐射触发CSP的形成,产生强,坚固的材料,具有很高的阻尼能力,模仿肌肉
科学领域:
- 材料科学
- 聚合物化学
- 生物仿真
背景情况:
- 肌肉收缩依赖于actin和myosin的相互作用,这种过程很难在人工聚合物中复制.
- 现有的人造肌肉缺乏对actin-myosin类相互作用的按需控制.
研究的目的:
- 开发一种新的聚合物系统,
- 创建具有增强材料特性和肌肉类功能的协同共价和超分子聚合物 (CSP).
主要方法:
- 通过光辐射诱导的四重H键构建了协同共价和超分子聚合物 (CSP).
- 研究了由此产生的CSP的网络结构和机械特性.
- 通过在位光触发的CSP形成证明了类似肌肉的功能,例如硬和自我生长.
主要成果:
- 实现独立形成的共价聚合物 (CP) 和超分子聚合物 (SP) 的按需组合.
- 开发出具有独特网络结构的CSP,具有协同效应,从而产生硬,坚固和坚固的材料.
- 具有很高的能量消耗能力 (>95%的抑制) 和模仿肌肉功能,如收缩诱导的硬化和训练诱导的自我增长.
结论:
- 通过协同CSP成功模仿了actin-myosin相互作用和肌肉收缩原理.
- 开发的CSP为创建由生物系统启发的新功能先进材料提供了一个有前途的平台.
- 这项工作为设计未来与软机器人和适应性材料应用的协同作用的CSP系统提供了基本的见解.
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