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相关概念视频

Molecular Models02:00

Molecular Models

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Physical models representing molecular architectures of chemical compounds play essential roles in understanding chemistry. The use of molecular models makes it easier to visualize the structures and shapes of atoms and molecules.
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Molecular Shapes01:18

Molecular Shapes

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Molecules have characteristic shapes that are crucial for their function. The arrangement of various electron groups around the central atom dictates their molecular geometry. Electron pairs in the valence shell of a central atom will adopt an arrangement that minimizes repulsions between the electron pairs by maximizing the distance between them. The valence electrons form either bonding pairs, located primarily between bonded atoms, or lone pairs.
Two regions of electron density in a diatomic...
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Ionic Crystal Structures02:42

Ionic Crystal Structures

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Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
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Protein Complexes with Interchangeable Parts01:57

Protein Complexes with Interchangeable Parts

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Groups of proteins may form a complex where each protein in this complex has a different role in the overall execution of the complex’s function. Often some of the proteins in the complex can be replaced by a closely related variant to give a complex that contains many of the same components yet is functionally distinct.
The SCF ubiquitin ligase is a protein complex of five individual proteins. This complex attaches ubiquitin to other target proteins to mark them for degradation. In order...
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Molecular and Ionic Solids02:54

Molecular and Ionic Solids

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Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
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Crystal Field Theory - Tetrahedral and Square Planar Complexes02:46

Crystal Field Theory - Tetrahedral and Square Planar Complexes

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Tetrahedral Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
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相关实验视频

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Self-assembly of Complex Two-dimensional Shapes from Single-stranded DNA Tiles
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类似俄罗斯娃娃的分子立方体

Die Liu1, Kaixiu Li2, Mingzhao Chen1

  • 1Institute of Environmental Research at Greater Bay Area; Key Laboratory for Water Quality and Conservation of the Pearl River Delta, Ministry of Education; Guangzhou Key Laboratory for Clean Energy and Materials, Guangzhou University, Guangzhou 510006, China.

Journal of the American Chemical Society
|December 30, 2020
PubMed
概括
此摘要是机器生成的。

研究人员使用金属有机自组制造了大型双超分子. 这些子内的结构模仿病毒体,并为分子识别和传递应用提供了潜力.

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科学领域:

  • 超分子化学
  • 材料科学
  • 纳米技术

背景情况:

  • 纳米化子内部化合物是先进的3D架构.
  • 合成模仿病毒体的多层超大是非常具有挑战性的.

研究的目的:

  • 为了合成新的,大型的双超分子.
  • 探索金属有机配体和金属离子的自组.
  • 创建功能识别,交付和检测的模型.

主要方法:

  • 易于与金属离子自组合的金属有机酸连接物.
  • 使用具有高几何约束的重新设计的连接体来形成独家的双.
  • 通过1H NMR,DOSY,ESI-MS,TWIM-MS,TEM,AFM和SAXS进行表征.

主要成果:

  • 已经成功合成了两个巨大的双超分子.
  • 具有内部立方体 (5.1 nm) 和外部截断立方体 (12.0 和 13.2 nm).
  • 达到了高分子量 (75,232 和 77,667 Da),是最大的合成内结构之一.

结论:

  • 通过连接体设计证明了离散的双结构的独占形成.
  • 合成的子作为超分子材料的优秀模型.
  • 突出了客分子识别,传递和检测的潜力.