多晶共价有机框架膜作为吸附剂而不是膜
Julie L Fenton1, David W Burke1, Dingwen Qian2
1Department of Chemistry, Northwestern University, Evanston, Illinois 60208, United States.
Journal of the American Chemical Society
|January 13, 2021
概括
共价有机框架 (COF) 材料是有效的吸附剂,而不是尺寸选择性的隔离膜. 它们的高容量吸附,由驱动,解释了之前观察到的"膜"性能.
科学领域:
- 材料科学
- 化学工程
- 分离科学
背景情况:
- 研究了共价有机框架 (COF) 以节能分离,据报道,厚薄膜通过尺寸选择性运输来分离各种分子.
- 之前的研究表明,COF膜通过有序的毛孔排除基于大小的分子.
研究的目的:
- 调查厚厚的多晶COF薄膜的实际分离机制.
- 为了确定COF薄膜是否作为尺寸选择性膜或作为吸附剂.
主要方法:
- 在COF粉末上测量了染料的吸附等温度.
- 使用计算建模来理解吸附热力学.
- 在不同的条件下 (体积,流量) 测试了COF颗粒的染料"排斥".
- 混合染料分离的实验是在流中进行的.
主要成果:
- 粉具有高吸收容量的染料,其亲和度跨越三级.
- 吸附行为与之前报告的"分离"性能相关.
- 计算分析将吸附差异与增量联系起来.
- COF颗粒显示体积和流量依赖的染料去除,与吸附相一致.
结论:
- 厚厚的多晶COF薄膜主要作为吸附剂而不是尺寸选择性膜.
- 在先前的研究中观察到的分离现象可以通过吸附机制来解释.
- 这些发现需要对COF膜文献进行重新评估.
- 基于孔隙传输的高效分离仍然是一个挑战.
更多相关视频
07:45Electrophoretic Crystallization of Ultrathin High-performance Metal-organic Framework Membranes
Published on: August 16, 2018
10.2K
06:45Author Spotlight: Characterizing Porous Materials for Aiding the Development of Robust Metal-Organic Frameworks with Adsorption Behavior
Published on: March 8, 2024
9.1K
相关概念视频
Detergent Purification of Membrane Proteins
5.5K
Detergents are used to purify the integral proteins of the membrane. The hydrophobic portion of the detergent can replace membrane phospholipids while solubilizing the membrane proteins. When detergent monomers reach a specific concentration in a solution called critical micelle concentration (CMC), they form micelles. Above CMC, the concentration of the detergent monomers remains in equilibrium with the micelle. The number of detergent monomers present in the CMC varies for each detergent, and...
5.5K
Solubility
16.9K
Solution, Solubility, and Solubility Equilibrium
A solution is a homogeneous mixture composed of a solvent, the major component, and a solute, the minor component. The physical state of a solution—solid, liquid, or gas—is typically the same as that of the solvent. Solute concentrations are often described with qualitative terms such as dilute (of relatively low concentration) and concentrated (of relatively high concentration).
In a solution, the solute particles (molecules,...
A solution is a homogeneous mixture composed of a solvent, the major component, and a solute, the minor component. The physical state of a solution—solid, liquid, or gas—is typically the same as that of the solvent. Solute concentrations are often described with qualitative terms such as dilute (of relatively low concentration) and concentrated (of relatively high concentration).
In a solution, the solute particles (molecules,...
16.9K
Assembly of the Lipid Bilayer in the ER
3.2K
Biological membranes are more than just a barrier separating cell cytoplasm from the outside environment. They are highly dynamic and help maintain the integrity and physiological stability of the cells as well as membrane-bound organelles. Membranes also play vital roles in cell-to-cell and intracellular communication.
A large chunk of any biological membrane is composed of phospholipids. These lipids have a heterogeneous distribution across different subcellular organelles and even between...
A large chunk of any biological membrane is composed of phospholipids. These lipids have a heterogeneous distribution across different subcellular organelles and even between...
3.2K
Colloidal precipitates
5.7K
The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...
5.7K
Ion Exchange
1.6K
Ion exchange chromatography separates charged molecules from a solution by reversibly exchanging them with mobile, or 'active', ions associated with the oppositely charged stationary phase. This method can be used to separate ions, soften and deionize water, and purify solutions. The polymers comprising the ion-exchange column are high-molecular-weight and chemically stable polymers, crosslinked to be porous and essentially insoluble. They are also functionalized with either acidic or...
1.6K
Analyte Adsorption and Distribution
2.8K
In certain chromatographic separations, solutes transfer between the mobile phase and the stationary phase via sorption, which typically refers to the process of adsorption. For many chromatographic systems, the sorption process often depends on the polarity of the compounds—an expression of the overall dipole moment within the molecule. During the separation process, there is competition between the solute and solvent for adsorption to the stationary phase. Highly polar compounds and...
2.8K
