从三组合碳化合物中进行单步乙烯净化
Baoyong Zhu1, Jian-Wei Cao2, Soumya Mukherjee3
1School of Chemistry and Chemical Engineering, Dezhou University, Dezhou 253023, P.R. China.
Journal of the American Chemical Society
|January 13, 2021
概括
研究人员开发了新的多孔材料,NPU-1/2/3,用于高效的乙烯分离. 这些材料选择性地吸附乙和乙,使混合C2碳化合物能够产生高纯度的乙.
科学领域:
- 材料科学
- 化学工程
- 分离科学
背景情况:
- 由于具有相似的物理性质,将乙烯与乙烯分离是具有挑战性的.
- 有效的乙烯生产需要先进的分离技术.
研究的目的:
- 为选择性C2碳化合物分离开发新型多孔材料.
- 在单个步骤中实现高纯度乙烯的生产.
主要方法:
- 基于六核金属集群的三种同结构多孔协调网络 (NPU-1,NPU-2,NPU-3) 的合成.
- 可调节尺寸的双结构的特征.
- 气体混合物分离的动态突破实验.
- 分子建模以了解吸附机制.
主要成果:
- NPU-1/2/3具有能够选择性吸附C2H2和C2H6而不是C2H4的双结构.
- 从C2H2/C2H4/C2H6混合物中获得>99.9%的纯度乙烯.
- 吸附选择性归因于结和内的非共价相互作用.
结论:
- 开发的多孔协调网络为高效的乙烯分离提供了有前途的解决方案.
- 可调节的双结构是实现C2碳化合物混合物的高选择性的关键.
- 这种方法使高纯度乙烯的生产具有成本效益.
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