在无孔,导电的二维协调聚合物中使用Li+离子间隔的高电容伪电容
Harish Banda1, Jin-Hu Dou1, Tianyang Chen1
1Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02138, United States.
Journal of the American Chemical Society
|February 2, 2021
概括
研究人员开发了一种用于电化学电容的新型无孔协调聚合物 (CP). 这种材料具有很高的导电性和伪电容离子间隔,提高了储能性能.
科学领域:
- 材料科学
- 电化学
- 能量储存
背景情况:
- 电化学电容器 (EC) 提供高功率密度,但受到低能量密度的限制.
- 高的特定表面积和电导率对于EC性能至关重要.
- 具有高导电性的无孔材料,如协调聚合物 (CP),在EC应用中经常被忽视.
研究的目的:
- 研究无孔协调聚合物 (CP) 作为电化学电容器 (EC) 的电极材料的潜力.
- 探索一种新的无孔CP,Ni3 (乙) (Ni3BHT),用于增强能量储存.
- 阐明Ni3BHT中用于高性能伪电容器的电荷存储机制.
主要方法:
- 一种新的无孔协调聚合物Ni3 (甲) (Ni3BHT) 的合成和表征.
- 在非水性电解质中测试Ni3BHT作为电极材料的电化学试验.
- 结构和电化学研究以确定电荷储存机制.
主要成果:
- Ni3BHT具有很高的电导率 (> 500 S/m).
- 电极性能显示出 245 F/g 和 426 F/cm3 的优异的特定容量.
- 利好性能归因于Ni3BHT的2D层之间的Li+离子的伪电容间隔.
结论:
- 在非多孔协调聚合物 (CP) 中首次证明了伪电容离子间隔.
- Ni3BHT对高能伪电容具有显著的潜力.
- 突出了探索无孔CP用于先进的电化学能量存储的巨大潜力.
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