在二维分层矿中,在相邻的量子洞之间进行电子转移
Zixi Yin1,2, Jing Leng1, Shiping Wang1,2
1State Key Laboratory of Molecular Reaction Dynamics and Dynamics Research Center for Energy and Environmental Materials, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China.
Journal of the American Chemical Society
|March 18, 2021
概括
研究人员在2D层的矿中发现了奥格尔辅助的电子转移,克服了量子井 (QW) 之间的绝缘障碍. 这一发现为先进的光电子设备提供了可调节的电荷传输.
科学领域:
- 材料科学
- 凝聚物质物理学
- 纳米技术
背景情况:
- 二维 (2D) 层叠的矿作为自然的多重量子井 (QW) 结构.
- 它们在光电子中的应用受阻于阻碍QW-QW载体运输的绝缘联体.
研究的目的:
- 研究和报告2D分层矿中载体转移的新机制.
- 解决QW之间能源障碍所造成的限制.
主要方法:
- 使用过渡吸收光谱来观察载体动态.
- 研究的 (CH2NH3) 2PbI42D矿具有特定的层数 (m=12,18).
主要成果:
- 在相邻的QW之间观察到Auger辅助的电子传输机制.
- 发现了一种长期存在的,类似衍生物的短暂吸收特征,
- 证明的电子能量屏障 (Eb) 与QW带间隙能量 (Eg) 相比.
结论:
- 这项研究确定了Auger辅助电子转移作为2D矿中可行的电荷传输途径.
- 为光学调节的QW到QW充电传输提供设计策略.
- 推进2D矿在光电子和光学调制应用中的潜力.
相关概念视频
The Energies of Atomic Orbitals
In an atom, the negatively charged electrons are attracted to the positively charged nucleus. In a multielectron atom, electron-electron repulsions are also observed. The attractive and repulsive forces are dependent on the distance between the particles, as well as the sign and magnitude of the charges on the individual particles. When the charges on the particles are opposite, they attract each other. If both particles have the same charge, they repel each other.
Atomic Radii and Effective Nuclear Charge
The elements in groups of the periodic table exhibit similar chemical behavior. This similarity occurs because the members of a group have the same number and distribution of electrons in their valence shells.
π Electron Effects on Chemical Shift: Overview
An applied magnetic field causes loosely bound π-electrons in organic molecules to circulate, producing a local or induced diamagnetic field over a large spatial volume. As the molecules tumble in solution, the field generated by π-electrons in spherical substituents results in a zero net field. However, the net field generated by π-electrons in non-spherical substituents is not zero. The effect of this induced field depends on the orientation of the molecule with respect to B0, resulting in...
Electric Field of Two Equal and Opposite Charges
Atoms generally contain the same number of positively and negatively charged particles, protons, and electrons. Hence, they are electrically neutral. However, the centers of the positive and negative charges do not always coincide. In such a scenario, the electric field of an atom may not be zero.
A separation of the positive and negative charges can lead to a weak, remnant effect of the positive and negative charges. The expectation is that the more the distance between the positive and...
A separation of the positive and negative charges can lead to a weak, remnant effect of the positive and negative charges. The expectation is that the more the distance between the positive and...
Electric Potential Energy of Two Point Charges
The electric potential energy of a test charge in a uniform eclectic field can be generalized to any electric field produced by static charge distribution. Consider a positive test charge in an electric field produced by another static positive charge. If the test charge is moved away from the static charge, then the electric field does the positive work on the test charge, and the electric potential energy of the test charge decreases as it moves away from the static charge. Here the electric...
Energy Associated With a Charge Distribution
The work done to bring a charge through a distance r is given by the potential difference between the initial and the final position. To assemble a collection of point charges, the total work done can be expressed in terms of the product of each pair of charges divided by their separation distance, defined with respect to a suitable origin. Solving this expression gives the energy stored in a point charge distribution.


