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Updated: Nov 8, 2025

Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
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Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

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嵌入曲烯单元中的1,3-二基基:单基与三基状态和平面内芳香度

Yuki Miyazawa1, Zhe Wang1, Misaki Matsumoto1

  • 1Department of Chemistry, Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima, Hiroshima 739-8526, Japan.

Journal of the American Chemical Society
|April 26, 2021
PubMed
概括

曲环烯 (CPP) 的大小决定了嵌入的1,3-二基 (DR) 的基本状态. 较大的DR-CPP表现出三重状态,而较小的则表现出单重状态,显示出尺寸依赖的旋转多重性控制.

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