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相关概念视频

Network Covalent Solids02:18

Network Covalent Solids

15.3K
Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
15.3K
Ionic Crystal Structures02:42

Ionic Crystal Structures

16.0K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
16.0K
Metallic Solids02:37

Metallic Solids

19.8K
Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
19.8K
Intermolecular Forces in Solutions02:28

Intermolecular Forces in Solutions

36.6K
The formation of a solution is an example of a spontaneous process, a process that occurs under specified conditions without energy from some external source.
When the strengths of the intermolecular forces of attraction between solute and solvent species in a solution are no different than those present in the separated components, the solution is formed with no accompanying energy change. Such a solution is called an ideal solution. A mixture of ideal gases (or gases such as helium and argon,...
36.6K
Molecular and Ionic Solids02:54

Molecular and Ionic Solids

18.9K
Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
18.9K
Lewis Structures of Molecular Compounds and Polyatomic Ions02:54

Lewis Structures of Molecular Compounds and Polyatomic Ions

41.4K
To draw Lewis structures for complicated molecules and molecular ions, it is helpful to follow a step-by-step procedure as outlined:
41.4K

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相关实验视频

Updated: Nov 7, 2025

Microfluidic-based Synthesis of Covalent Organic Frameworks COFs: A Tool for Continuous Production of COF Fibers and Direct Printing on a Surface
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Microfluidic-based Synthesis of Covalent Organic Frameworks COFs: A Tool for Continuous Production of COF Fibers and Direct Printing on a Surface

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二维共价有机框架固体溶液

Rebecca L Li1, Anna Yang1, Nathan C Flanders1

  • 1Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208 United States.

Journal of the American Chemical Society
|April 28, 2021
PubMed
概括
此摘要是机器生成的。

研究人员使用单体混合物创建了新的共价有机框架 (COF). 这一突破允许通过调整固体溶液中的单体比率来持续调整孔径大小等COF属性.

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Microfluidic-based Synthesis of Covalent Organic Frameworks COFs: A Tool for Continuous Production of COF Fibers and Direct Printing on a Surface
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Synthesis of Single-Crystalline Core-Shell Metal-Organic Frameworks
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科学领域:

  • 材料科学
  • 聚合物化学
  • 纳米技术

背景情况:

  • 共价有机框架 (COF) 通常使用有限的单体来实现高对称性结构.
  • 用多个单体合成COF通常会导致统计分布或较低的对称性.

研究的目的:

  • 从不同长度的单体混合物中演示单相二维COF固体溶液的形成.
  • 探索设计具有可调节性质的复杂COF的新策略.

主要方法:

  • 使用可变料比率的单体混合物的聚合.
  • 使用X射线衍射,里埃变换红外光谱和Pawley精细化进行了表征.

主要成果:

  • 形成具有连续可变格子参数的单相六边形二维COF固体溶液.
  • 同一个格子内的单体的随机分布,通过衍射和光谱学证实.
  • 通过非线性格子参数变化显示的不同长度的单体的结合曲折的证据.

结论:

  • 固体溶液形成为设计具有更高复杂性的二维COF提供了新的途径.
  • 可调节的单体成分允许对COF属性进行持续控制,例如平均孔径.
  • 混合物的直接聚合是有效的,而合成后的链接器交换不适合形成固体溶液.