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一种基于组件的实用合成途径,使得林科萨胺抗生素在北半球容易多样化

Matthew J Mitcheltree1, Jack W Stevenson1, Amarnath Pisipati1

  • 1Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138, United States.

Journal of the American Chemical Society
|April 30, 2021
PubMed
概括

一种新的合成途径可以为林科萨米德抗生素制造多种氨基糖碎片. 这种灵活的方法利用醇化学和甘环氧化物用于新药发现.

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Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.
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