弱溶解溶液可使高能离子电池的石墨-SiO阳极进行化学预化
Jinkwan Choi1,2, Hyangsoo Jeong3, Juyoung Jang4,5
1Center for Energy Storage Research, Korea Institute of Science and Technology (KIST), 02792 Seoul, Korea.
Journal of the American Chemical Society
|June 10, 2021
概括
化学预石化提高了离子电池的初始库伦比效率 (ICE). 这种方法实现了近乎理想的能量密度和完整电池的周期寿命.
科学领域:
- 材料科学
- 电化学
- 电池技术
背景情况:
- 初始库伦比效率 (ICE) 对离子电池的能量密度至关重要,尤其对于下一代阳极.
- 石混合阳极具有平衡的容量和循环寿命,但存在低ICE,阻碍了商业化.
研究的目的:
- 开发一种化学预化方法以最大限度地提高混合阳极的ICE.
- 研究+间隔机制,并防止化前的结构降解.
- 在使用预化阳极的完整电池中实现近乎理想的能量密度.
主要方法:
- 使用可调节的烯复合溶液,具有可调节的溶解功率,用于化学化.
- 使用混合光谱和密度函数理论 (DFT) 计算来研究Li+间隔机制.
- 研究的溶解规则,以控制+的溶解,并减轻对石墨的插入.
主要成果:
- 使用预化混合阳极达到506Wh kg-1 (98.6%的理想) 的全电池能量密度.
- 经过250个循环后,证明了87.3%的容量保留.
- 确定弱溶解溶液抑制了溶解离子间隔,使稳定的先化成为可能.
结论:
- 化学化是提高高容量阳极性能的一种有前途的策略.
- 这种方法可以开发具有更好的ICE和能量密度的实用高能离子电池.
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