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相关概念视频

Network Covalent Solids02:18

Network Covalent Solids

Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
Step-Growth Polymerization: Overview01:03

Step-Growth Polymerization: Overview

Step-growth or condensation polymerization is a stepwise reaction of bi or multifunctional monomers to form long-chain polymers. As all the monomers are reactive, most of the monomers are consumed at the early stages of the reaction to form small chains of reactive oligomers, which then combine to form long polymer chains in the late stages. Hence, the reaction has to proceed for a long time to achieve high molecular weight polymers.
Many natural and synthetic polymers are produced by...
Additives and Fillers in Concrete01:29

Additives and Fillers in Concrete

Additives and fillers are integral to enhancing the properties of concrete. Pozzolans and blast-furnace slag are additives or admixtures due to their reactions with calcium hydroxide released during cement hydration. Fillers, which are finely ground and similar in fineness to Portland cement, improve concrete attributes such as workability density, and reduce capillary bleeding or cracking. Some fillers possess hydraulic properties or participate in benign reactions within the cement paste.
The...

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相关实验视频

Updated: May 8, 2026

Fabrication of Fully Solution Processed Inorganic Nanocrystal Photovoltaic Devices
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Fabrication of Fully Solution Processed Inorganic Nanocrystal Photovoltaic Devices

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无机材料的合理固态合成路径

Muratahan Aykol1, Joseph H Montoya1, Jens Hummelshøj1

  • 1Toyota Research Institute, Los Altos, California 94022, United States.

Journal of the American Chemical Society
|June 11, 2021
PubMed
概括

这项研究提出了一种设计无机化合物合成的新方法,通过基于晶体能量和特性来预测反应的成功. 它可以有效地规划新材料的发现.

科学领域:

  • 固态化学
  • 材料科学
  • 计算化学

背景情况:

  • 无机固态合成的合理设计仍然具有挑战性.
  • 预测成功的合成途径需要了解核化障碍和阶段选择性.
  • 现有的方法往往缺乏对各种无机目标的预测能力.

研究的目的:

  • 为无机化合物的合理固态合成制定预测方法.
  • 使用计算数据开发一种识别有利合成反应的方法.
  • 展示这种方法在各种无机材料的反应规划中的应用.

主要方法:

  • 在晶体反应物上以催化核合成形式进行固态合成.
  • 通过高通量热化学数据获得的反应和界面能量来估计核化障碍.
  • 使用结构和界面晶体特征进行能量近似.
  • 采用帕雷托分析来根据核化障碍和相选择性确定有利的反应.

主要成果:

  • 在LiCoO2,BaTiO3和YBa2Cu3O7合成反应规划中成功应用.
  • 扩展到其他金属氧化物,氧化物,酸盐和化物.
  • 提供了无机化合物的反合成框架.

更多相关视频

Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of ChalcogenidoplumbatesII or IV
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Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of ChalcogenidoplumbatesII or IV

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Author Spotlight: Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
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Author Spotlight: Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers

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相关实验视频

Last Updated: May 8, 2026

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Author Spotlight: Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
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Author Spotlight: Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers

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结论:

  • 开发的方法使固态无机合成的合理设计和有效规划成为可能.
  • 这种方法通过预测合成的成功来促进新无机材料的发现.
  • 这种方法为复杂无机化合物的逆合成提供了途径.