在碳孔中封闭的离子液体中"巨大的"吸收
Ipek Harmanli1,2, Nadezda V Tarakina1, Markus Antonietti1
1Department of Colloid Chemistry, Research Campus Golm, Max Planck Institute of Colloids and Interfaces, Am Mühlenberg 1, 14476 Potsdam, Germany.
Journal of the American Chemical Society
|June 15, 2021
概括
孔封闭可显著增加酸乙 (EmimOAc) 等离子液体 (ILs) 的吸收量,高达十倍. 这种增强在微孔和添加碳材料中最为明显.
科学领域:
- 材料科学
- 化学工程
- 物理化学
背景情况:
- 离子液体具有较高的气体吸收能力.
- 孔封闭是提高IL气体吸收的一种方法.
- 1- 乙基-3- 甲基乙酸 (EmimOAc) 是一种代表性的IL.
研究的目的:
- 研究碳物质结构对孔封闭的EmimOAc中吸收的影响.
- 量化由于孔隙封闭而增加的吸收.
- 了解孔径大小 (微孔与中孔) 和碳材料中 doping 的作用.
主要方法:
- 使用四种碳材料的矩阵,具有不同的孔结构 (微孔/半孔) 和 doping.
- 使用热重量计分析 (TGA) 和差分扫描热量计 (DSC) 来观察封闭效应.
- 进行了标准体积吸附实验,以量化孔内EmimOAc的吸收.
主要成果:
- 当被限制在碳孔中时,EmimOAc中的吸收增加了多达10倍.
- 在微孔和添加碳材料中观察到最显著的吸收增强.
- 封闭效应足以被TGA和DSC检测到.
结论:
- 孔封闭会大大增加离子液体中的吸收.
- 碳材料的特性,特别是微孔性和兴奋剂,对于最大化这种增强至关重要.
- 这种增强的吸收归因于离子在狭窄空间中的分子排列,为气创造了额外的自由体积.
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