在共结晶过程中可视化和操纵固态分子运动
Haoran Wang1,2, Qiyao Li1, Jianyu Zhang1
1Department of Chemistry, Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction, Department of Chemical and Biomedical Engineering, Institute for Advanced Study, and Guangdong Hong Kong Macro Joint Laboratory of Optoelectronic and Magnetic Functional Materials, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, China.
Journal of the American Chemical Society
|June 21, 2021
概括
这项研究可视化和操纵多组件共晶体中的固态分子运动,使信息存储和动态防伪的新应用成为可能.
科学领域:
- 材料科学
- 超分子化学
- 化学结晶学
背景情况:
- 固态分子运动 (SSMM) 对材料属性至关重要,但在多元件系统中没有得到充分研究.
- 在研究和控制SSMM方面存在挑战,特别是在复杂的材料组件中.
研究的目的:
- 在二元共晶系统中可视化和操纵SSMM.
- 探索新型共晶体的聚合诱导排放 (AIE) 特性.
- 在实际应用中应用SSMM诱导的排放变化.
主要方法:
- 在FSBO/TCB和PVBO/TCB系统中使用Cocrystal工程.
- 在不同压力和温度下监测SSMM的光光谱.
- 在1D封闭环境中对分子移动性的研究.
主要成果:
- FSBO/TCB (F/T) 合晶体显示开启光;PVBO/TCB (P/T) 合晶体显示红移发射,两者都有AIE特性.
- 研磨混合物显示出通过光变化可观察到的明显的SSMM.
- 在FSBO/TCB中观察到显著的分子运动 (4毫米) 在1D管内没有研磨.
结论:
- 多组件共晶体中的SSMM可以使用光可视化和操纵.
- 对SSMM的独特排放反应为信息存储和动态防伪提供了潜力.
- 这项研究为多元组件聚合科学和SSMM提供了宝贵的见解.
相关概念视频
Crystal Growth: Principles of Crystallization
3.5K
Crystallization is a phase transformation process in which crystals are precipitated from a supersaturated solution or formed from other sources. During crystallization, atoms or molecules arrange themselves into a well-defined, rigid crystal lattice to minimize energy.
Initiating crystallization involves manipulating the concentration of the solute and the temperature of the solution. Since crystal growth occurs when the ratio of concentration and solubility of the solute in the solvent...
Initiating crystallization involves manipulating the concentration of the solute and the temperature of the solution. Since crystal growth occurs when the ratio of concentration and solubility of the solute in the solvent...
3.5K
Recrystallization: Solid–Solution Equilibria
1.6K
Recrystallization is a purification technique used to separate impurities from solid compounds. In this technique, no chemical reactions occur. Instead, it exploits physical properties only, specifically, the solubility differences between the desired compound and impurities, either at a single temperature or at different temperatures, and under other selected conditions. The solid-solution equilibrium (solubility equilibrium) of each component in the solution represents a binary phase...
1.6K
Molecular and Ionic Solids
18.8K
Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
18.8K


