基于聚合物的大面积,灵活,透明和长寿命的光膜
Yongfeng Zhang1, Yan Su1, Hongwei Wu2,3
1School of Materials Science and Engineering, Chongqing University of Technology, Chongqing 400054, China.
Journal of the American Chemical Society
|August 19, 2021
概括
基于聚合物的灵活,透明的室温光材料 (RTP) 使用结策略开发. 这些材料具有长寿命的余光,可用于有机电子和灵活的3D发光装置.
科学领域:
- 材料科学
- 有机电子
- 光物理学
背景情况:
- 基于聚合物的室温光材料 (RTP) 由于灵活性和大面积生产,为有机电子提供了前景.
- 在室温下填充和稳定三重激发状态存在挑战,以获得高效的RTP.
研究的目的:
- 开发具有长寿命的大型,灵活和透明的RTP材料.
- 研究结合和联合组装在实现稳定的RTP中的作用.
主要方法:
- 将有机染色体 (3,6-二-9H-碳醇和7H-二[c,g]碳醇) 添加到聚乙醇 (PVA) 基质中.
- 使用结和联合组装策略来增强RTP特性.
- 描述光发射,光照持续时间和发光强度.
主要成果:
- 具有长寿命光 (长达2044.86毫秒) 和余光 (超过20秒) 的灵活透明RTP膜.
- 在DPCz合PVA薄膜中证明了高绝对发光率 (158.4 mcd m2).
- 通过结抑制非辐射衰变,并通过联合组装最小化单体-三体能量差距.
结论:
- 开发的RTP材料具有出色的机械性能和后照性能.
- 成功制造出灵活的3D物体和多通道后发光二极管阵列
- 提供了生产先进,大面积,灵活和透明发射材料的可行途径.
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