一种无金属的分子抗铁电材料,具有高相位过渡温度和大电热效应
Haojie Xu1,2, Wuqian Guo1,2, Jiaqi Wang1
1State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, People's Republic of China.
Journal of the American Chemical Society
|August 30, 2021
概括
我们发现了环甲基化物 (CMB), 由于CMB具有显著的电热效应,因此它是环保固态制冷技术的有希望的候选者.
科学领域:
- 材料科学
- 固态物理
- 热力学
背景情况:
- 由于其电热效应,抗铁电 (AFE) 材料对固态制冷具有前景.
- 目前的研究重点是无机氧化物,但由于环境原因需要无金属替代品.
研究的目的:
- 引入一种新的无金属分子抗铁电材料,即环甲基化物 (CMB).
- 调查其相位转换,电极化和冷却应用的电热性质.
主要方法:
- 环甲基化物 (CMB) 的合成和表征
- 使用电气测量进行温度依赖相变的分析.
- 通过极化电场歇斯底里循环评估电热效应.
主要成果:
- CMB在364-368 K左右呈现反铁电 - 铁电 - 准电相变.
- 实现了~6μC/cm2的实际电极化.
- 在20kV/cm的电场下显示了显著的正和负电热温度变化 (ΔT为4.2K和-3K).
结论:
- CMB是一种有前途的无金属分子反铁电材料,用于固态冷却.
- 它的独特机制涉及阳离子重定位和离子位移,与无机氧化物不同.
- 强调开发环保制冷设备的潜力.
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