一种新的六边形纳米板催化剂,用于选择性CO2转化为乙醇
Jie Yin1,2, Zhouyang Yin1, Jing Jin2
1Department of Chemistry, Brown University, Providence, Rhode Island 02912, United States.
Journal of the American Chemical Society
|September 14, 2021
概括
研究人员开发了铁磁六角密封的纳米片,用于选择性减少二氧化碳到乙醇. 这种催化剂显示出高效率和选择性,为可持续化学生产提供了有前途的途径.
科学领域:
- 电化学
- 材料科学
- 催化剂
背景情况:
- 二氧化碳还原反应 (CO2RR) 对可持续的化学合成至关重要.
- 开发可选择性催化剂使CO2RR成为像乙醇这样有价值的产品仍然是一个挑战.
研究的目的:
- 报告一种基于铁磁六边密封 (hcp) (Co) 纳米片 (NSs) 的新型催化剂,用于选择性CO2RR对乙醇 (CH3CHO).
主要方法:
- 使用hcp CoN 作为催化剂的二氧化碳的电化学减少.
- 在0.5MKHCO3溶液中,降解电位从-0.2到-1.0V (相对于RHE) 不同.
- 密度函数理论 (DFT) 计算以阐明反应机制.
主要成果:
- 在所有测试的潜力中,hcp CoNS选择性地生产了乙醇作为主要产品.
- 在 -0.4 V 时,乙醇的法拉代效率 (FE) 达到 60%,电流密度为 5.1 mA cm-2 和质活性为 3.4 A g-1.
- 乙醇,乙醇和甲醇的总FE为82%.
结论:
- hcp Co 催化剂对乙醇的 CO2RR 具有很高的选择性.
- DFT计算表明,层内电子转移促进[OC-CO]*合并抑制完全化,导致选择性CH3CHO的形成.
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