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Updated: Oct 20, 2025

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
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从分子碳化物平台的线性碳化合物链生长

Jun Ohata1, Akira Teramoto1, Hiroaki Fujita1

  • 1Department of Chemistry, Graduate School of Science, Osaka Prefecture University, Sakai, Osaka 599-8531, Japan.

Journal of the American Chemical Society
|September 15, 2021
PubMed
概括

研究人员使用碳化平台逐步增长直线碳化合物链到C6. 这一突破模仿了Fischer-Tropsch合成,通过代增加CH2单元来延长链条.

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The radical chain-growth polymerization mechanism consists of three steps: initiation, propagation, and termination of polymerization. The polymerization initiates when a free radical generated from the radical initiator adds to the unsaturated bond in the monomer. The unpaired electron of the free radical and one π electron in the unsaturated bond creates a σ bond between the free radical and the monomer. As a result, the other π electron in the unsaturated bond converts this...
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