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相关概念视频

Metallic Solids02:37

Metallic Solids

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Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
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Voltaic/Galvanic Cells02:47

Voltaic/Galvanic Cells

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Spontaneous Chemical Reactions
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
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Batteries and Fuel Cells

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A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
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Ionic Crystal Structures02:42

Ionic Crystal Structures

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Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
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Standard Electrode Potentials03:02

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On comparing the reactivity of silver and lead, it is observed that the two ionic species, Ag+ (aq) and Pb2+ (aq), show a difference in their redox reactivity towards copper: the silver ion undergoes spontaneous reduction, while the lead ion does not. This relative redox activity can be easily quantified in electrochemical cells by a property called cell potential. This property is commonly known as cell voltage in electrochemistry, and it is a measure of the energy which accompanies the charge...
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When two or more atoms come together to form a molecule, their atomic orbitals combine and molecular orbitals of distinct energies result. In a solid, there are a large number of atoms, and therefore a large number of atomic orbitals that may be combined into molecular orbitals. These groups of molecular orbitals are so closely placed together to form continuous regions of energies, known as the bands.
The energy difference between these bands is known as the band gap.
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用于固态电池的铜协调纤维素离子导体

Chunpeng Yang1, Qisheng Wu2, Weiqi Xie1

  • 1Department of Materials Science and Engineering, University of Maryland, College Park, MD, USA.

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|October 21, 2021
PubMed
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研究人员开发了一种新的固体聚合物离子导体,用于更安全的高能电池. 通过在纤维素中使用铜离子设计分子通道, 他们实现了快速的离子运输和出色的电化学稳定性.

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科学领域:

  • 材料科学
  • 电化学
  • 聚合物科学

背景情况:

  • 固态金属电池提供高能量密度和安全性,但面临当前固态离子导体的挑战.
  • 无机导体提供快速的离子传输,但缺乏接口接触;聚合物导体提供兼容性,但离子导电性较低.
  • 现有的离子导体难以满足先进电池操作的要求.

研究的目的:

  • 为先进的电池开发高性能固体聚合物离子导体.
  • 在聚合物中设计分子通道以增强离子传输和电化学稳定性.
  • 展示一个可通用的策略来创建高效的固态离子导体.

主要方法:

  • 协调铜离子 (Cu2+) 与一维纤维素纳米纤维形成分子通道.
  • 研究了沿着工程聚合物链运输的离子 (Li+).
  • 描述了新导体的离子导电性,转移数和电化学稳定性窗口.

主要成果:

  • 在分子链方向上达到高Li+导电性 (1.5 × 10-3 S/cm).
  • 证明了高转移率 (0.78) 和广泛的电化学稳定性窗口 (0-4.5V).
  • 验证了该方法与其他聚合物和的通用性,显示了各种应用的潜力.

结论:

  • 聚合物中的分子通道工程是高性能固体离子导体的可行策略.
  • 配合Cu2+的纤维素导体可以在高能量密度电池的厚阴极中进行离子透.
  • 这种方法对开发安全,高性能固态电池具有广泛的影响,超出目前的限制.