来自含有有机的复合材料系统的明亮高效敏感近红外光发光
Chen Lyu1, Hongfei Li1, Shufang Zhou1
1Materials Research Institute and Department of Physics and Astronomy, Queen Mary University of London, Mile End Road, London E14NS, United Kingdom.
Journal of the American Chemical Society
|October 22, 2021
概括
使用有机敏感剂实现了 (Nd3+) 离子的强烈近红外 (NIR) 辐射. 这种新材料系统为集成光学提供了高效的光发射.
科学领域:
- 材料科学
- 光电子产品
- 无机-有机混合系统
背景情况:
- 有机发光材料通常缺乏先进光学应用所需的狭窄发射线宽和特定波长.
- 新 (Nd3+) 离子表现出特有的近红外 (NIR) 辐射,但高效的激发和高量子产量是具有挑战性的.
研究的目的:
- 开发一种高效的有机-无机混合材料,用于强烈和窄线宽的NIR发射.
- 使用复合有机敏感剂增强 Nd3+ 离子的敏感化和激发效率.
- 探索这种材料系统在集成光学中的潜力.
主要方法:
- 含有 (Nd3+) 离子的有机-无机复合系统的制造.
- 使用复合有机敏化剂以有效地传递能量给 Nd3+ 离子.
- 光发光特性,包括发射强度,线宽和量子效率的表征.
主要成果:
- 通过 Nd3+ 离子实现强烈的 NIR 发射,其强度与有机半导体发射器相当.
- 在低激发功率下通过高效的敏感化效应,提高了 Nd3+ 排放的约 3000 倍.
- 在高度的Nd3+下,性能优化,有机化系统的量子效率约为40%.
结论:
- 开发的材料系统表现出高效的 Nd3+ NIR 发射与狭窄的线宽.
- 高效的传感效应和高量子效率使该系统对光电子设备具有前景.
- 对薄膜的适用性支持其在集成光学中的应用.
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