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Updated: Oct 14, 2025

Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance
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用于湿度控制应用的化学稳定的基于碳素的共价有机框架

Leisan Gilmanova1, Volodymyr Bon1, Leonid Shupletsov1

  • 1Chair of Inorganic Chemistry I, Technische Universität Dresden, Bergstraße 66, 01069 Dresden, Germany.

Journal of the American Chemical Society
|November 2, 2021
PubMed
概括

新的共价有机框架 (COF) 具有卓越的稳定性和多孔性,可有效控制室内湿度. 这些材料具有可逆的pH依赖性质,并具有先进的湿度管理应用的潜力.

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Basicity of Heterocyclic Aromatic Amines

Heterocyclic amines, where the N atom is a part of an alicyclic system, are similar in basicity to alkylamines. Interestingly, the heterocyclic amine having a nitrogen atom as part of an aromatic ring has much less basicity than its corresponding alicyclic counterpart. For this reason, as presented in Figure 1, piperidine (pKb = 2.8) is significantly more basic than pyridine (pKb = 8.8).
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