红色光碳量子点 基于有机框架的电解发光二极管 超过5%的外部量子效率
Yuxin Shi1, Zhibin Wang2, Ting Meng1
1Key Laboratory of Theoretical & Computational Photochemistry of Ministry of Education, College of Chemistry, Beijing Normal University, Beijing 100875, China.
Journal of the American Chemical Society
|November 8, 2021
概括
研究人员开发了红色光碳量子点有机框架 (CDOF),用于高效的电发光LED. 这些新型CDOF实现了高量子产量,使显示器能够发出更明亮,更高效的红光.
科学领域:
- 材料科学
- 纳米技术
- 光电子产品
背景情况:
- 由于稳定性和环保性,碳量子点 (CQD) 对照明具有前景.
- 光CQD的外部量子效率 (EQE) 限制在5%以下,这是由于旋转禁止的三重过渡.
- 有效的红色发射对于全彩显示器至关重要,但对于CQD来说具有挑战性.
研究的目的:
- 合成红色光碳量子点有机框架 (CDOF).
- 为了实现高效的红色光发光二极管 (LED).
- 克服光CQD在显示应用中的效率限制.
主要方法:
- 红色光碳量子点有机框架 (CDOF) 的合成
- 使用CDOF制造和表征发光LED.
- 测量光发光的量子产量,发光强度和EQE.
主要成果:
- 获得了高达42.3%的量子产量红色光CDOF.
- 已证明高效的红色光电解灯,最大发光率为1818cdm-2.
- 红色光灯的EQE达到5.6%.
结论:
- 光CQD,特别是CDOF,可以克服光CQD的效率限制.
- 开发的CDOF可以实现高性能红色电光灯.
- 这项工作为基于CQD的高性能电光装置开辟了新的途径.
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