接近二维半导体二极管的内在激子物理极限
Peng Chen1, Timothy L Atallah1, Zhaoyang Lin1
1Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA, USA.
Nature
|November 18, 2021
概括
我们尽量减少二维半导体二极管的界面障碍, 这表明激子扩散和Auger重组是设备性能和效率的关键.
科学领域:
- 材料科学
- 凝聚物质物理学
- 纳米技术
背景情况:
- 由于其降低的维度,二维 (2D) 半导体具有独特的光物理特性.
- 基本的二维半导体光物理与实用的设备性能之间存在差距,通常受到界面障碍的限制.
- 接触诱导的重组阻碍了二维半导体器件内在光物理学的实现.
研究的目的:
- 抑制接触诱导的重组,并实现 2D 半导体二极管内在光物理学的装置性能.
- 研究2D半导体器件中激子动态和电荷相互作用的作用.
- 探索基于2D半导体内在特性创建更高效的光电子设备的潜力.
主要方法:
- 使用最小界面干扰的范德瓦尔斯接触器制造二维半导体二极管.
- 用于在二二氧化 (WSe2) 中独立调节电子和孔.
- 采用时间分辨率光发光和扫描光电流显微镜来研究光物理性质和设备性能.
主要成果:
- 通过抑制Shockley-Read-Hall重组实现了几乎内在的光物理指定的设备性能.
- 在低电荷密度下观察到短路光流的异常峰值.
- 由于激素-充电Auger重组,激素寿命显著减少.
结论:
- 激子扩散有限模型成功解释了电荷密度依赖的短路光电流.
- 突出了激子扩散和二体激子-电荷Auger重组在二维设备中的关键作用.
- 展示了利用内在2D半导体光物理学的潜力,以提高光电子设备的效率.
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