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光化学形式的 (4 + 2) 循环添加因胺替代的Bicyclo[1.1.1]和

Alexander S Harmata1, Taylor E Spiller1, Madison J Sowden1

  • 1Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, United States.

Journal of the American Chemical Society
|December 13, 2021
PubMed
概括

这项研究引入了一种新的光化学方法,用于将双环[1.1.1]-1-胺转化为多种双环[3.1.1]-1-胺. 这种突破性的合成为药物化学应用提供了有价值的sp3丰富的原始氨基.

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