在水气转移反应期间,Au和Pt在基于CeO的催化剂上保持不氧化
Tomas R Reina1,2, Miriam Gonzalez-Castaño1, Victor Lopez-Flores1,3
1Inorganic Chemistry Department and Materials Science Institute, University of Seville─CSIC, 41092 Sevilla, Spain.
Journal of the American Chemical Society
|December 20, 2021
概括
在水气转移反应中,黄金和催化剂仍然是金属的. 金纳米粒子动态重组, 而粒子稳定, 揭示了有效催化的主要见解.
科学领域:
- 催化剂
- 材料科学
- 表面化学
背景情况:
- 在水气转移 (WGS) 反应中, (CeO2) 基催化剂中的黄金 (Au) 和 (Pt) 的活性物种尚未完全理解.
- 潜在的活性位点包括影响氧气流动性的离子物种或与氧气空位相互作用的金属接口.
研究的目的:
- 使用支持催化剂阐明WGS反应期间Au和Pt的氧化状态和动态行为.
- 将观察到的金属动态与催化活性相关联,并了解金属支相互作用的作用.
主要方法:
- 在现场使用X射线吸收光谱 (XAS) 来监测WGS反应条件下的催化剂.
- 分析的重点是确定Au和Pt纳米粒子的氧化状态和结构演变.
主要成果:
- 在WGS反应中,Au和Pt都被证实保持其金属 (无氧化) 状态.
- (Pt0) 纳米粒子重组为立方体形状,没有显著的尺寸变化,与转化增加相关.
- 黄金 (Au) 纳米粒子表现出动态行为,包括分裂和聚合,即使在非金属环境中也保持金属状态.
结论:
- 当Au原子被氧包围时,WGS反应活性较高,这表明了关键的静电相互作用.
- 这些发现突出了Au和Pt在反应条件下的不同动态行为,强调了金属支相互作用和静电力在WGS反应中的高催化性能的重要性.
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