在电池操作过程中分离的动态空间进展
Fang Liu1, Rong Xu1, Yecun Wu2
1Department of Materials Science and Engineering, Stanford University, Stanford, CA, USA.
Nature
|December 23, 2021
概括
电池中孤立的 (i-Li) 并没有死亡,而是动态移动,影响电池性能. 这项研究显示,
科学领域:
- 材料科学
- 电化学
- 能量储存
背景情况:
- 下一代储能需要高性能电池.
- 由于固体电解质接口和孤立的 (i-Li) 形成,当前的阳极受到容量衰减和短周期寿命的影响.
- 孤立的通常被认为是电化学不活跃的,导致容量损失.
研究的目的:
- 挑战孤立的 (i-Li) 是电化学不活跃的假设.
- 研究电池中的i-Li的动态行为和电化学反应.
- 探索恢复i-Li和提高电池性能的方法.
主要方法:
- 使用模拟来分析i-Li在电场下的行为.
- 研究i-Li的动态,包括其末端的沉积和溶解.
- 在Cu-Li细胞和LiNi0.5Mn0.3Co0.2O2 (NMC) -Li全细胞中进行了实验.
主要成果:
- 通过动态极化证明i-Li对电池操作具有高度响应性.
- 在i-Li端观察到同时的沉积和溶解,导致空间进展.
- 模拟结果表明i-Li的进展速度取决于其长度,方向和电流密度.
- 通过回收i-Li,在Cu-Li细胞中达到>100%的库伦比效率.
- 延长了NMC-Li细胞的循环寿命.
结论:
- 隔离的 (i-Li) 是电化学活性,并在电池中动态移动.
- 了解和控制i-Li的行为对于提高电池性能和寿命至关重要.
- 恢复i-Li为提高电池的库伦比效率和循环寿命提供了一个有希望的策略.
更多相关视频
11:25Identification and Quantification of Decomposition Mechanisms in Lithium-Ion Batteries; Input to Heat Flow Simulation for Modeling Thermal Runaway
Published on: March 7, 2022
4.8K
08:11Failure Analysis of Batteries Using Synchrotron-based Hard X-ray Microtomography
Published on: August 26, 2015
9.0K
相关概念视频
Batteries and Fuel Cells
28.4K
A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
28.4K
Voltaic/Galvanic Cells
58.9K
Spontaneous Chemical Reactions
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
58.9K
DC Battery
924
A conductor needs to be a component of a path that creates a closed loop or full circuit to have a continuous current flowing through it. A current starts to flow if an electric field is created inside an isolated conductor that is not part of a full circuit. The conductor quickly develops a net positive charge at one end and a net negative charge at the other. These charges generate an electric field opposite the direction of the applied electric field, which reduces the current. Eventually,...
924
Formation of Complex Ions
24.2K
A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
24.2K
Mania and Antimanic Drugs: Overview
363
Mania, a psychological condition characterized by elevated mood, increased energy, and reduced sleep need, is part of the bipolar disorder cycle. The exact cause of mania isn't entirely known, but it is thought to be a combination of genetic, environmental, and neurological factors. Bipolar disorder involves alternating manic and depressive episodes. Mood stabilizers like lithium, antipsychotics, and anticonvulsants help manage these episodes. Lithium carbonate is particularly effective as...
363
Trends in Lattice Energy: Ion Size and Charge
24.9K
An ionic compound is stable because of the electrostatic attraction between its positive and negative ions. The lattice energy of a compound is a measure of the strength of this attraction. The lattice energy (ΔHlattice) of an ionic compound is defined as the energy required to separate one mole of the solid into its component gaseous ions. For the ionic solid sodium chloride, the lattice energy is the enthalpy change of the process:
24.9K
