带有巨型磁电合的铁弹性旋转交叉复合体中的域壁动力学
Vibe Boel Jakobsen1, Elzbieta Trzop2, Emiel Dobbelaar1
1School of Chemistry, University College Dublin, Belfield, Dublin 4, Ireland.
Journal of the American Chemical Society
|December 23, 2021
概括
这项研究揭示了一种具有铁弹性域壁和两步旋转状态切换的新复合体. 这些特性源于合的结构和旋转顺序,导致旋转交叉材料的多功能性.
科学领域:
- 材料科学
- 固态化学
- 磁力学和螺旋电子学
背景情况:
- 旋转交叉 (SCO) 材料基于外部刺激提供可调节的磁性.
- 了解结构性,磁性和电性之间的相互作用对于先进的材料设计至关重要.
- 铁弹性和极相是多铁应用的关键特征.
研究的目的:
- 在Mn (III) 复合体中研究结构和旋转状态顺序参数之间的合.
- 在机械应力下检测和描述铁弹性域壁.
- 探索材料的多功能潜力,包括磁电合.
主要方法:
- 单晶X射线衍射以确定晶体结构和相变.
- 共振超声谱检测铁弹性和机械性能.
- 对磁电合和电极化的测量.
主要成果:
- 确定了三种不同的突破对称的相位过渡 (Cc → Pc → P1 → P1 ((1/2)).
- 在应对机械应力时观察到铁弹性域壁.
- 在脉冲磁场下检测到电极化和残余极化的显著变化.
结论:
- (III) 复合体在应变,极化,结构和旋转状态顺序参数之间表现出强烈的合.
- 这种材料表现出多功能性,展示铁弹性,极相和旋转交叉行为.
- 这些发现突出了潜在应用的旋转交叉材料中偶联订单参数的罕见例子.
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