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双中的无孔适应晶体可逆捕获

Dan Luo1, Yanlei He1, Jinya Tian1

  • 1State Key Laboratory of Materials Processing and Die & Mold Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China.

Journal of the American Chemical Society
|December 28, 2021
PubMed
概括

一个富含的新能有效地捕获各种形式的放射性, 这对于核安全和废物管理至关重要. 捕获的可以释放到受控反应中,并且子可以多次重复使用.

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Bromination and chlorination of aromatic rings by electrophilic aromatic substitution reactions are easily achieved, but fluorination and iodination are difficult to achieve. Fluorine is so reactive that its reaction with benzene is difficult to control, resulting in poor yields of monofluoroaromatic products. To address this, Selectfluor reagent is used as a fluorine source in which a fluorine atom is bonded to a positively charged nitrogen.
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