增加电池充电电压的正反机制
Yoko Hase1, Takeshi Uyama1, Kiho Nishioka2
1Toyota Central R&D Laboratories, Inc., 41-1 Yokomichi, Nagakute, Aichi 480-1192, Japan.
Journal of the American Chemical Society
|January 11, 2022
概括
氧电池的充电过量源于Li2-O2脱过程中的正反循环. 抑制氧化率,电压或Li+扩散的变化可以提高电池的效率.
科学领域:
- 电化学
- 材料科学
- 能量储存
背景情况:
- 非水性O2电池的充电潜力过大,导致效率低和材料降解.
- 复杂的反应机制阻碍了对这些过度潜力的完全理解.
研究的目的:
- 调查在充电过程中导致过量的特定反应步骤.
- 阐明增加电池电压的正反机制的起源.
主要方法:
- 使用Rietveld精制的现场粉末X射线衍射.
- 采用了静电间歇定位技术 (GITT).
- 分析了Li2-O2相的结构和电化学特性.
主要成果:
- 在充电过程中发现了缺乏的2-O2相.
- 确定固体溶液解作为速度决定的步骤.
- 随着电压的增加,观察到Li+扩散系数 (DLi) 的下降,导致氧化率减速和电压增加.
结论:
- 一个正反循环在初始充电阶段内在增加电池电压.
- 通过稳定氧化率,电池电压和DLi来延长充电过程的连续性.
相关概念视频
Charging Conductors By Induction
8.4K
The Earth is a good conductor of electricity, and it is so big that it can be considered an infinite source or sink of charges. It can easily exchange charges with any matter.
Generally, conductors like metals do not allow any excess charge to be present on them. Any excess charge added to metals easily flows away, for example, when a metal is placed on the Earth. This process is called earthing.
However, conductors can be charged by a process called induction. For example, consider charging a...
Generally, conductors like metals do not allow any excess charge to be present on them. Any excess charge added to metals easily flows away, for example, when a metal is placed on the Earth. This process is called earthing.
However, conductors can be charged by a process called induction. For example, consider charging a...
8.4K
Batteries and Fuel Cells
28.3K
A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
28.3K
Oscillations In An LC Circuit
2.5K
An idealized LC circuit of zero resistance can oscillate without any source of emf by shifting the energy stored in the circuit between the electric and magnetic fields. In such an LC circuit, if the capacitor contains a charge q before the switch is closed, then all the energy of the circuit is initially stored in the electric field of the capacitor. This energy is given by
2.5K
DC Battery
915
A conductor needs to be a component of a path that creates a closed loop or full circuit to have a continuous current flowing through it. A current starts to flow if an electric field is created inside an isolated conductor that is not part of a full circuit. The conductor quickly develops a net positive charge at one end and a net negative charge at the other. These charges generate an electric field opposite the direction of the applied electric field, which reduces the current. Eventually,...
915
Voltaic/Galvanic Cells
58.8K
Spontaneous Chemical Reactions
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
58.8K
Voltage Doubler Circuit
955
A voltage doubler circuit integrates two main components: a clamping section and a rectifier section. The clamping section consists of a capacitor (C1) and a diode (D1), whereas the rectifier section is equipped with another diode (D2) and capacitor (C2). This circuit produces an output voltage with twice the amplitude of the sinusoidal input voltage.
955


