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相关概念视频

Electrolyte and Nonelectrolyte Solutions02:21

Electrolyte and Nonelectrolyte Solutions

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Substances that undergo either a physical or a chemical change in solution to yield ions that can conduct electricity are called electrolytes. If a substance yields ions in solution, that is, if the compound undergoes 100% dissociation, then the substance is a strong electrolyte. Complete dissociation is indicated by a single forward arrow. For example, water-soluble ionic compounds like sodium chloride dissociate into sodium cations and chloride anions in aqueous solution.
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Batteries and Fuel Cells03:12

Batteries and Fuel Cells

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A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
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Electrolysis03:00

Electrolysis

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In a galvanic cell, the electrical work is done by a redox system on its surroundings as electrons produced by the spontaneous redox reactions are transferred through an external circuit. Alternatively, an external circuit does work on a redox system by imposing a voltage sufficient to drive an otherwise nonspontaneous reaction in a process known as electrolysis. For instance, recharging a battery involves the use of an external power source to drive the spontaneous (discharge) cell reaction in...
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Trends in Lattice Energy: Ion Size and Charge02:54

Trends in Lattice Energy: Ion Size and Charge

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An ionic compound is stable because of the electrostatic attraction between its positive and negative ions. The lattice energy of a compound is a measure of the strength of this attraction. The lattice energy (ΔHlattice) of an ionic compound is defined as the energy required to separate one mole of the solid into its component gaseous ions. For the ionic solid sodium chloride, the lattice energy is the enthalpy change of the process:
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Ionic Bonds00:42

Ionic Bonds

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Overview
When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
Ionic bonds are reversible electrostatic interactions between ions...
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Introduction to Electrolytes01:33

Introduction to Electrolytes

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In humans, electrolytes play a vital role in various physiological processes. Balancing electrolyte levels is essential for normal body functions; their imbalance can be life-threatening. The major electrolytes include sodium, potassium, chloride, calcium, phosphate, and bicarbonate. They are primarily involved in physiological processes, such as nerve signal transmission, membrane trafficking, muscle contraction, buffering body fluids, and balancing water levels in the body.
Role of Sodium
One...
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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

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用于高能固态电池的弹性体电解质

Michael J Lee1, Junghun Han2, Kyungbin Lee1

  • 1George W. Woodruff School of Mechanical Engineering, Georgia Institute of Technology, Atlanta, GA, USA.

Nature
|January 13, 2022
PubMed
概括
此摘要是机器生成的。

研究人员开发了新的弹性固态电解质,用于更安全,高能固态电池. 这些先进的电解质克服了当前材料的局限性,使金属阳极具有稳定的性能.

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Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature
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Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature

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Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries Using Synchrotron Radiation Techniques
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Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries Using Synchrotron Radiation Techniques
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科学领域:

  • 材料科学 材料科学 材料科学
  • 电化学 电化学 电化学
  • 储能 储能 储能 储能 储能 储能

背景情况:

  • 具有金属阳极的固态电池是传统离子电池的有希望的替代品.
  • 当前的固态电解质在实际应用中面临机械性能和电化学性能方面的挑战.
  • 树的生长是金属电池的主要安全问题.

研究的目的:

  • 开发具有改进的机械和电化学性能的先进固态电解质.
  • 为了实现高能固态电池使用金属阳极的安全高效运行.
  • 解决现有的固态电解质在实际电池应用中的局限性.

主要方法:

  • 制造具有3D互连的塑料晶相的弹性固态电解质.
  • 在铜上的弹性体电解质的现场形成,用于涂/脱落.
  • 在受限制条件下测试使用高负荷阴极 (LiNi0.83Mn0.06Co0.11O2) 的全电池.

主要成果:

  • 弹性体电解质具有机械强度,高离子导电性和低界面电阻.
  • 由于体积变化适应,实现了100.0%的库伦比克效率,用于和剥离.
  • 在4.5伏和环境温度下表现出稳定的全电池运行,提供>410Wh/kg的特定能量.

结论:

  • 新型弹性固态电解质为稳定,高能固态电池提供了可行的策略.
  • 这一进步解决了金属电池在机械稳定性和电化学性能方面的关键挑战.
  • 开发的系统为下一代储能解决方案铺平了道路.