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Updated: Oct 6, 2025

Preparation of Polyoxometalate-based Photo-responsive Membranes for the Photo-activation of Manganese Oxide Catalysts
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Preparation of Polyoxometalate-based Photo-responsive Membranes for the Photo-activation of Manganese Oxide Catalysts

Published on: August 7, 2018

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由电荷转移驱动的氧进化反应从Cr复合物转移到含有多氧金属酸盐的多孔离子晶体

Yuto Shimoyama1, Naoki Ogiwara1, Zhewei Weng1

  • 1Department of Basic Science, School of Arts and Sciences, The University of Tokyo, Komaba, Meguro-ku, Tokyo 153-8902, Japan.

Journal of the American Chemical Society
|January 18, 2022
PubMed
概括

具有多氧金属酸盐 (Co-POM) 的多孔离子晶体 (PIC) 显示出高效的氧化演化反应 (OER) 催化. 这项研究澄清了协同机制,揭示了组件之间的电荷转移在非基本条件下增强了催化活性.

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Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
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