在低电场下,Relaxor铁电聚合物表现出极高的电机学合
Xin Chen1, Hancheng Qin2, Xiaoshi Qian3
1Department of Materials Science and Engineering, Materials Research Institute, The Pennsylvania State University, University Park, PA 16802, USA.
概括
研究人员通过添加化单体来增强铁电聚合物的电机械 (EM) 合. 这种创新提高了聚合物的性能,
科学领域:
- 材料科学
- 聚合物科学
- 凝聚物质物理学
背景情况:
- 电机 (EM) 合,即电能和机械能的相互转换,对于各种应用中使用的铁电材料至关重要.
- 铁电聚合物通常具有弱电磁合,限制了它们的实用性.
- 现有的铁电聚合物难以满足先进技术应用的性能要求.
研究的目的:
- 为了增强铁电聚合物的机电合.
- 改善放松性铁电性聚合物的极化特性.
- 开发一种与陶压电材料相竞争的聚合物材料.
主要方法:
- 将少量的 (<2mol%) 化 (FA) 单体纳入放松性铁电聚合物 (PVDF-TrFE-CFE) 聚合物中.
- 在低直流偏差场 (40 MV/m) 下对修改的聚合物极化行为和电磁合的描述.
主要成果:
- 通过添加FA单体,显著增强了极化变化和强烈的电磁合.
- 抑制非贡献性的偏振变化,从而提高能量转换效率.
- 在修改后的放松型聚合物中,达到88%的电磁合系数 (k33) 和压电系数 (d33) >1000 pm/V.
结论:
- 添加FA单体显著提高了铁电聚合物的机电合和压电特性.
- 通过溶液处理的聚合物表现出与氧化陶压电器相匹配的性能.
- 这一突破为灵活,高性能压电聚合物的新应用提供了潜力.
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