在高温下有效捕获低度的化学稳定共价有机框架
Zhiyuan Zhang1, Xinglong Dong2, Jun Yin2
1School of Materials Science and Engineering, National Institute for Advanced Materials, TKL of Metal and Molecule-Based Material Chemistry, Nankai University, Tianjin 300350, P. R. China.
Journal of the American Chemical Society
|April 5, 2022
概括
一种新的基于的共价有机框架 (COF),TGDM,在恶劣的工业条件下有效地捕获放射性 (I2). 与目前用于核废物再处理的银基吸附剂相比,TGDM具有更高的吸收和稳定性.
科学领域:
- 材料科学
- 化学工程
- 核化学
背景情况:
- 由于高温和低度,从核废物中捕获放射性 (I2) 蒸气具有挑战性.
- 目前的工业吸附剂和基于银的材料在核燃料再加工方面具有效率和成本的限制.
研究的目的:
- 在工业条件下开发一种新型吸收剂.
- 与现有技术相比,评估新吸附剂的性能,稳定性和成本效益.
主要方法:
- 合成一种称为TGDM的基共价有机框架 (COF).
- 在150°C和150 ppmv I2的TGDM吸附能力的表征.
- 理论计算以了解吸附机制.
- 化学和热稳定性,可回收性和成本的评估.
主要成果:
- 在150°C和150ppmv的I2中,TGDM的I2吸收率高达~30%,超过了基于银的工业吸收剂 (例如17%的Ag@MOR).
- 在TGDM内的离子位点通过强大的库伦相互作用进行吸附.
- TGDM表现出卓越的化学和热稳定性,满足高温,潮湿和酸性环境的要求.
- 与目前的工业吸附剂相比,该材料具有更高的可回收性和更低的成本.
结论:
- 在核燃料再加工中,TGDM是放射性I2蒸汽捕获的非常有希望的候选者.
- 在COF中加入稳定的离子guanidine部分为开发先进的I2吸附剂提供了可行的策略.
- TGDM的性能,稳定性和成本优势解决了当前技术的主要局限性.
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