单晶丰富阴极中的平面滑动的动力起源
Xin-Hai Meng1,2, Ting Lin3,2, Huican Mao3
1CAS Key Laboratory of Molecular Nanostructure and Nanotechnology, Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P.R. China.
Journal of the American Chemical Society
|June 14, 2022
概括
研究人员研究了单晶丰富的阴极,发现减少氧气空缺可以防止滑动和裂. 这提高了下一代电池的循环稳定性.
科学领域:
- 材料科学
- 电化学
- 固态化学
背景情况:
- 单晶丰富的阴极具有高容量,但由于平面滑动和裂纹而遭受循环不稳定.
- 这些问题损害了阴极的完整性,导致电池的容量大大降低.
研究的目的:
- 研究单晶Ni丰富阴极中的平面滑动的起源和演变.
- 确定减轻滑动和微裂变的策略,以提高阴极性能和稳定性.
主要方法:
- 表面分析揭示滑翔飞机和重建的表面.
- 在滑翔过程中研究过渡金属离子的飞机内迁移.
- 与迁移能量障碍相关的氧空度.
主要成果:
- 确定了新的表面曝光,包括 (003) 滑翔平面和重建的 (-108) 表面,由表面能量驱动.
- 证明滑翔涉及到平面过渡金属离子迁移.
- 表明减少氧气空缺增加了迁移能量屏障,有效地限制了滑动和微裂纹.
结论:
- 控制氧气空缺对于提高单晶丰富阴极的化学性能至关重要.
- 在袋式电池 1000 次循环后,设计的缺氧阴极保持了 80.8% 的容量.
- 这些发现为改善先进电池材料的循环稳定性提供了缺陷控制的见解.
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