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具有强光热效应的长度刺激的原子精度Au42纳米棒
Yingwei Li1, Yongbo Song2, Xinwen Zhang3
1Department of Chemistry, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213, United States.
Journal of the American Chemical Society
|June 29, 2022
概括
研究人员创造了类似分子的金纳米棒 (Au42),具有强烈的近红外吸收和高效的光热转换,模仿金属纳米棒的潜在生物医学应用.
科学领域:
- 纳米技术
- 材料科学
- 物理化学
背景情况:
- 金属金纳米棒在近红外 (NIR) 区域显示强烈的纵向等离子激发,非常适合光热转换.
- 在~2nm以下的金纳米结构成为非金属,引发了关于纳米棒中保持纵向激发的问题.
研究的目的:
- 研究原子精确的棒状金纳米结构的光学和光热特性.
- 确定分子样金纳米棒是否可以表现出强烈的纵向激发和高效的光热转换.
主要方法:
- 原子精确的棒形Au42 ((SCH2Ph) 32纳米集群的合成.
- 使用UV-Vis光谱和短暂吸收光谱进行表征.
- 光热转换效率的测量
- 密度函数理论 (DFT) 的计算.
主要成果:
- 具有高面积比率 (6.2) 的Au42纳米棒在815nm时显示强烈的NIR吸收 (分子吸收率:1.4 × 10^5 M^-1 cm^-1).
- 在808nm激发时,有效的光热转换在5分钟内增加~27°C.
- DFT计算证实了沿着长轴的NIR过渡,类似于纵向激发振荡.
- 过渡吸收显示了快速衰变,随后是缓慢衰变,寿命长 (2400 ns).
结论:
- 这项研究展示了分子类纳米棒中强烈的纵向激发的第一个实例.
- Au42纳米棒具有高效的光热转换,适用于生物医学治疗,光声成像和光催化.
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