用于从空气中捕获二氧化碳的共价有机框架
Hao Lyu1, Haozhe Li1, Nikita Hanikel1
1Department of Chemistry and Kavli Energy Nanoscience Institute, University of California, Berkeley, Berkeley, California 94720, United States.
Journal of the American Chemical Society
|July 5, 2022
概括
研究人员开发了一种将氨基物种纳入共价有机框架 (COF) 的新方法. 这大大增加了二氧化碳 (CO2) 的捕获,特别是来自空气等稀释来源的碳.
科学领域:
- 材料科学
- 化学工程
- 环境科学
背景情况:
- 共价有机框架 (COF) 是具有调节性质的多孔材料.
- 开发高效的二氧化碳捕获材料对于缓解气候变化至关重要.
- 将反应性功能组纳入COF可以增强它们的气体吸附能力.
研究的目的:
- 在COF中首次对反应性亚胺物种进行共价结合.
- 开发一种新的合成策略,用于制造高亲和度的二氧化碳化学吸收剂.
- 在不同的湿度条件下研究改性COF的二氧化碳吸收能力.
主要方法:
- 一种因胺结合的COF (COF-609-Im) 的结晶.
- 通过aza-Diels-Alder循环添加,将伊胺链转化为四氨基.
- 在框架中合三氨基胺.
- 使用同位素标记的里埃变换红外光谱和固态核磁共振光谱进行表征.
主要成果:
- 与原始框架相比,修改后的COF-609的二氧化碳吸收增加了1360倍.
- 在湿度存在时,还观察到二氧化碳吸收增加了29%.
- 框架转化化学和增强的二氧化碳吸收得到实验证实.
结论:
- 建立了一种新型合成策略来制造氨基功能化COF.
- 由此产生的COF-609具有特殊的二氧化碳捕获性能,特别是来自稀释源.
- 这项工作为碳捕获应用开发先进的化学吸收剂提供了有前途的途径.
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