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Updated: Sep 5, 2025

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加化:一种高选择性的无氧化脱催化剂

Yong Yuan1, Jason S Lee1, Raul F Lobo1

  • 1Center for Catalytic Science and Technology, Department of Chemical and Biomolecular Engineering, University of Delaware, Newark, Delaware 19716, United States.

Journal of the American Chemical Society
|July 6, 2022
PubMed
概括

化热质有效催化脱,在热质孔中形成活跃的 Ga+ 位点. 通过多环芳去活化是可逆的,强调Ga+是这种反应的关键活性中心.

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Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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