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Updated: Aug 29, 2025

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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在四碳酸催化反应中C-H插入,尽管有分裂的动态趋势:对反应效率和催化剂设计的影响

Wentao Guo1, Stephanie R Hare1, Shu-Sen Chen1

  • 1Department of Chemistry, University of California, Davis, California 95616, United States.

Journal of the American Chemical Society
|September 13, 2022
PubMed
概括

Rh催化的C-H插入反应可以产生多个产物. 最初的分子动力学模拟揭示了催化剂设计,特别是使用更大的腔和特定的替代剂,如何控制对所需β-lactones的选择性.

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