在高压下分层的范德瓦尔斯化中的超导性
Yilian Xi1,2,3, Xiaoling Jing4, Zhongfei Xu1,2,5
1School of Physics, Beihang University, Beijing100191, China.
Journal of the American Chemical Society
|October 4, 2022
概括
在压力下观察到二维化 (GeH) 的超导性,即使在过渡到无形阶段后也持续存在. 这种无形相表现出增强的超导性,为无形化物超导提供了新的见解.
科学领域:
- 凝聚物质物理学
- 材料科学
- 固态化学
背景情况:
- 在二维 (2D) 材料的超导性是很难理解的.
- 在二维系统中,超导性可以持续存在, 尽管存在混乱和对称性破裂.
研究的目的:
- 在压力下研究2D范德瓦尔斯化 (GeH) 的结构和超导过渡.
- 探索无形化物相中的超导机制.
主要方法:
- 在现场高压同步射线衍射
- 在现场高压拉曼光谱
- 传输电子显微镜
- 密度函数理论模拟
主要成果:
- 在8.39GPa时,GeH具有5.41K的临界温度 (Tc).
- 在16.80 GPa时,晶体转变为无形,并保持超导.
- 在减压过程中,在二维无形阶段观察到Tc增加到6. 11K.
结论:
- 2D vdW GeH 的超导性与费米级的状态密度增加以及在压力下增强的电子-声子合有关.
- 压力诱导过渡到无形阶段为研究无形化物超导提供了一个新系统.
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