在具有异常大的光透深度的阿佐比斯皮拉中进行光控制的能量储存
Alejandra Gonzalez1, Magdalena Odaybat2, My Le1
1Department of Chemistry, Brandeis University, 415 South Street, Waltham, Massachusetts 02453, United States.
Journal of the American Chemical Society
|October 12, 2022
概括
新的阿扎比斯皮拉光开关可以在凝结阶段有效储存太阳能. 这些材料具有可逆光切换和高能量密度,与电池相比,具有深度光透.
科学领域:
- 材料科学
- 摄影化学
- 能量储存
背景情况:
- 分子光开关对于储能应用至关重要.
- 开发具有高能量密度和高效光吸收的材料至关重要.
研究的目的:
- 研究用于凝聚相光切换和太阳能储存的亚比斯皮拉衍生物.
- 探索结构修改对光交换和储能性能的影响.
主要方法:
- 用不同的终端替代剂合成和表征阿佐比斯皮拉衍生物.
- 在紫外线和可见光照射下对凝聚阶段的光切换行为进行调查.
- 测量能量储存密度和光透深度.
主要成果:
- 在室温下,阿佐比斯皮拉衍生物表现出轻易可逆光转换.
- 实现了前所未有的大有效光透深度 (1400微米).
- 在紫外线照射下观察到晶体到液体相变,导致能量储存密度> 300 J/g.
结论:
- 结构设计,包括 heteroarene, ortho-methyl 替代剂和终端组,显著影响冷凝相切换和能量储存.
- 这些发现为开发新型分子太阳能储能材料提供了设计原则.
更多相关视频
06:08Time-resolved Photophysical Characterization of Triplet-harvesting Organic Compounds at an Oxygen-free Environment Using an iCCD Camera
Published on: December 27, 2018
9.0K
07:12Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
Published on: July 17, 2020
6.3K
相关概念视频
Photosystem I
64.0K
Although structurally similar to photosystem II (PSII), photosystem I (PSI) is has a different electron supplier and electron acceptor.
Both these photosystems work in concert. An excited electron from PSII is relayed to PSI via an electron transport chain in the thylakoid membrane of the chloroplast, which is comprised of the carrier molecule plastoquinone, the dual-protein cytochrome complex, and plastocyanin. As electrons move between PSII and PSI, they lose energy and must be re-energized...
Both these photosystems work in concert. An excited electron from PSII is relayed to PSI via an electron transport chain in the thylakoid membrane of the chloroplast, which is comprised of the carrier molecule plastoquinone, the dual-protein cytochrome complex, and plastocyanin. As electrons move between PSII and PSI, they lose energy and must be re-energized...
64.0K
The Z-Scheme of Electron Transport in Photosynthesis
10.4K
The light reactions of photosynthesis assume a linear flow of electrons from water to NADP+. During this process, light energy drives the splitting of water molecules to produce oxygen. However, oxidation of water molecules is a thermodynamically unfavorable reaction and requires a strong oxidizing agent. This is accomplished by the first product of light reactions: oxidized P680 (or P680+), the most powerful oxidizing agent known in biology. The oxidized P680 that acquires an electron from the...
10.4K
Photosystem II
72.2K
The multi-protein complex photosystem II (PS II) harvests photons and transfers their energy through its bound pigments to its reaction center, and ultimately to photosystem I (PSI) through the electron transport chain. The pigments responsible for caputirng the light energy in photosystems include chlorophyll a, chlorophyll b, and carotenoids.
The pigment molecules are arranged across two photosystem domains — the antenna complex and the reaction center. The main aim of the pigment...
The pigment molecules are arranged across two photosystem domains — the antenna complex and the reaction center. The main aim of the pigment...
72.2K
The Antenna Complex
6.2K
Plants and other photosynthetic organisms comprise pigments capable of absorption of direct sunlight. These pigments are present in the reaction center - the main site of photochemical reactions as well as in the antenna complex. Under average light conditions, the rate at which reaction center pigments absorb light is far below the electron transport chain's capacity. As a result, the reaction center alone cannot provide enough energy to drive photosynthesis. The photosynthetic efficiency can...
6.2K
Photoluminescence: Applications
473
Photoluminescence offers a wide range of applications due to its inherent sensitivity and selectivity. This technique allows for both direct and indirect analyses of the analyte. Direct quantitative analysis is possible when the analyte exhibits a favorable quantum yield for fluorescence or phosphorescence. However, an indirect analysis may be feasible if the analyte is not fluorescent or phosphorescent, or if the quantum yield is unfavorable. Indirect methods include reacting the analyte with...
473
Photoreceptors and Plant Responses to Light
21.3K
Light plays a significant role in regulating the growth and development of plants. In addition to providing energy for photosynthesis, light provides other important cues to regulate a range of developmental and physiological responses in plants.
21.3K
