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相关概念视频

Catalysis02:50

Catalysis

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The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed during the process. A basic comprehension of a catalysts’ role during chemical reactions can be understood from the concept of reaction mechanisms and energy diagrams.
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Electron Configuration of Multielectron Atoms03:26

Electron Configuration of Multielectron Atoms

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The alkali metal sodium (atomic number 11) has one more electron than the neon atom. This electron must go into the lowest-energy subshell available, the 3s orbital, giving a 1s22s22p63s1 configuration. The electrons occupying the outermost shell orbital(s) (highest value of n) are called valence electrons, and those occupying the inner shell orbitals are called core electrons. Since the core electron shells correspond to noble gas electron configurations, we can abbreviate electron...
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Reduction of Alkenes: Catalytic Hydrogenation02:13

Reduction of Alkenes: Catalytic Hydrogenation

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Alkenes undergo reduction by the addition of molecular hydrogen to give alkanes. Because the process generally occurs in the presence of a transition-metal catalyst, the reaction is called catalytic hydrogenation.
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
The hydrogenation process takes place on the...
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Turnover Number and Catalytic Efficiency01:19

Turnover Number and Catalytic Efficiency

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The turnover number of an enzyme is the maximum number of substrate molecules it can transform per unit time. Turnover numbers for most enzymes range from 1 to 1000 molecules per second. Catalase has the known highest turnover number, capable of converting up to 2.8×106 molecules of hydrogen peroxide into water and oxygen per second. Lysozyme has the lowest known turnover number of half a molecule per second.
Chymotrypsin is a pancreatic enzyme that breaks down proteins during digestion....
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相关实验视频

Updated: Aug 23, 2025

Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction
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Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction

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Pt原子单层催化剂嵌入缺陷丰富的Ceria以实现高效的CO氧化

Shaohua Xie1, Liping Liu2, Yue Lu3

  • 1Department of Civil, Environmental, and Construction Engineering, Catalysis Cluster for Renewable Energy and Chemical Transformations (REACT), NanoScience Technology Center (NSTC), University of Central Florida, Orlando, Florida 32816, United States.

Journal of the American Chemical Society
|November 2, 2022
PubMed
概括

具有可控协调结构的单原子催化剂可促进碳氧化. 在-支上嵌入原子单层显示出卓越的活性和稳定性.

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科学领域:

  • 催化剂
  • 材料科学
  • 表面化学

背景情况:

  • 金属位点的局部协调结构对于支持的金属催化剂性能至关重要.
  • 控制单原子催化剂的协调环境是优化它们的活动的关键.

研究的目的:

  • 在-支上制造具有受控局部协调环境的原子单层 (PtASL) 结构.
  • 调查Pt1局部协调对还原激活过程中的催化活性和结构演变的影响.

主要方法:

  • 用于制造PtASL结构的表面缺陷丰富策略.
  • Pt1局部协调和分散的特征
  • 对CO氧化的催化活性进行评估.

主要成果:

  • 通过精确控制的嵌入和吸附PtASL结构实现100%的金属分散.
  • 嵌入式PtASL的转换频率比吸附式PtASL的转换频率高3.5倍.
  • 与Pt单原子相比,嵌入的PtASL显示出10-70倍的活性 (Pt1).
  • 有利的CO吸附和增强的格子氧激活有助于比嵌入式PtASL更好的CO氧化.

结论:

  • Pt1的局部协调环境显著影响催化活性和结构稳定性.
  • 嵌入式PtASL在ceria-alumina上为高性能催化剂提供了一个有希望的途径.
  • 精确控制金属位点协调使原子利用率达到100%和最佳的催化活性.