完全描述LaCl3-NaCl溶解结构和导致结构异质性的间隔盐的概念
Matthew S Emerson1, Shobha Sharma1, Santanu Roy2
1Department of Chemistry, The University of Iowa, Iowa City, Iowa 52242, United States.
Journal of the American Chemical Society
|November 15, 2022
概括
盐结构是稀土分离的关键. 这项研究显示,由于热能,溶盐中的化物离子存在于多个相互竞争的协调状态,而不是单一的主导状态.
科学领域:
- 材料科学
- 物理化学
- 核工程
背景情况:
- 兰化物是盐反应器 (MSR) 中的关键裂变产物.
- 了解盐中的化物结构对于通过盐电解分离和回收稀土元素至关重要.
- 关于化盐结构的现有文献是零碎的,通常是矛盾的.
研究的目的:
- 在整洁和混合中统一理解兰他尼德局部和中间范围的结构.
- 解决有关La3+协调,网络结构和衍射峰的来源的具体问题.
- 为了协调X射线散射,拉曼光谱和模拟结果.
主要方法:
- 对X射线散射和拉曼光谱数据的分析.
- 与模拟结果进行比较.
- 在不同温度下研究LaCl3和LaCl3-NaCl混合物.
主要成果:
- 对于溶盐中的M3+离子来说,单一的主导协调状态的概念是不准确的.
- 多个相互竞争的协调状态存在,并因热能相互转换.
- 在纯的LaCl3中,第一个明显的衍射峰值 (FSDP) 是中等范围的指示,混合物中出现了新的峰值.
结论:
- 放弃溶盐中M3+离子单一突出的协调状态的概念.
- 采用一个由温度影响的多个,动态交换的协调状态的模型.
- 通过综合实验和模拟方法可以实现对盐结构的统一理解.
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