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Updated: Aug 18, 2025

Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
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Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks

Published on: June 9, 2023

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用于氧电池的可调节的d频段调节氧化的原子金属有机框架

Qingliang Lv1, Zhuo Zhu1,2, Youxuan Ni1

  • 1Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (RECAST), College of Chemistry, Nankai University, Tianjin300071, China.

Journal of the American Chemical Society
|December 7, 2022
PubMed
概括

在基于的金属有机框架 (NiRu-HTP) 中原子分散的通过增强反应动力学和减少过量的电位,显著提高了氧电池的性能. 这种催化剂的设计促进了有效的Li2O2形成和分解,使其具有出色的循环利用性.

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Metal-Ligand Bonds02:51

Metal-Ligand Bonds

The hemoglobin in the blood, the chlorophyll in green plants, vitamin B-12, and the catalyst used in the manufacture of polyethylene all contain coordination compounds. Ions of the metals, especially the transition metals, are likely to form complexes.
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
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