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Ionic Strength: Effects on Chemical Equilibria01:19

Ionic Strength: Effects on Chemical Equilibria

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The addition of an inert ionic compound increases the solubility of a sparingly soluble salt. For example, adding potassium nitrate to a saturated solution of calcium sulfate significantly enhances the solubility of calcium sulfate. Le Châtelier's principle cannot predict this shift in the equilibrium. Instead, this could be explained in terms of changes in the effective concentration of the ions in solution in the presence of added inert salt.
In this solution, the primary...
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Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

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Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
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Formation of Complex Ions03:45

Formation of Complex Ions

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A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
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Ionic Strength: Overview01:12

Ionic Strength: Overview

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The ionic strength of a solution is a quantitative way of expressing the total electrolyte concentration of a solution. This concept was first introduced in 1921 by two American physical chemists, Gilbert N. Lewis and Merle Randall, while describing the activity coefficient of strong electrolytes. During the calculation of ionic strength (I or μ), all the cations and anions are considered. However, the concentration (c) of an ion with a greater charge number (z) has a greater contribution...
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Ionic Bonds00:42

Ionic Bonds

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Overview
When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
Ionic bonds are reversible electrostatic interactions between ions...
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Theory of Metallic Conduction01:17

Theory of Metallic Conduction

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The conduction of free electrons inside a conductor is best described by quantum mechanics. However, a classical model makes predictions close to the results of quantum mechanics. It is called the theory of metallic conduction.
In this theory, Newton's second law of motion is used to determine the acceleration of an electron in the presence of an applied electric field. Then, its velocity is expressed via this acceleration.
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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
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增强离子导电性的高机制

Yan Zeng1, Bin Ouyang1,2,3, Jue Liu4

  • 1Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA.

Science (New York, N.Y.)
|December 22, 2022
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概括

高材料显著提高了先进电池的固体电解质的离子导电性. 这一突破提高了合成能力,并减少了对固态电池特定化学物质的依赖.

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科学领域:

  • 材料科学
  • 电化学
  • 固态电池

背景情况:

  • 固态电池需要高效的固体电解质来提高安全性和性能.
  • 超离子导电结构框架是推进固体电解质技术的关键.

研究的目的:

  • 研究高性金属离子混合物对固体电解质的离子导电性的影响.
  • 通过高设计来证明增强合成性和降低化学特异性.

主要方法:

  • 在超离子导体结构中加入高性金属阴离子.
  • 在改造的Li-NASICON,Na-NASICON和Li-garnet材料中对离子导电性的实验验证.
  • 分析局部扭曲和离子透路径.

主要成果:

  • 高会导致离子导电率的增加.
  • 在 (Li) - (Na) 超离子导体 (Li-NASICON),Na-NASICON和Li-garnet结构中观察到增强的离子导电性.
  • 局部扭曲促进了离子的低激活能量透.

结论:

  • 高工程是设计优质固体电解质的有希望的策略.
  • 这种方法为克服传统固体电解质化学的局限性提供了途径.
  • 提供设计新型高超声波导体的见解.