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Updated: Aug 13, 2025

[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
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基于YIII-氨酸平台的分子工程双基

Nithin Suryadevara1,2, Athanassios K Boudalis2,3,4, Jorge Enrique Olivares Peña1

  • 1Institute of Nanotechnology (INT), Karlsruhe Institute of Technology (KIT), Eggenstein-LeopoldshafenD-76344, Germany.

Journal of the American Chemical Society
|January 19, 2023
PubMed
概括

合成的 (III) 双层复合物被合成二基. 这些双根在刚性上表现出旋转移位,在最短的绑定双根C1中"旋转泄漏"最为明显.

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Radical reactions can occur either intermolecularly or intramolecularly. In an intermolecular radical reaction, a nucleophilic radical adds to an electrophilic alkene or vice versa. In such reactions, the radical and generally the alkene, which is also called the radical trap, are two different molecules. Additionally, for such intermolecular reactions to occur, the radical trap must be active, present in an excess concentration, and the radical starting material must have a weak...
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