在非富勒烯受体的多晶层中的极光子
Lixuan Liu1,2,3, Zhixiang Wei2,3, Stefan C J Meskers1
1Molecular Materials and Nanosystems, Institute for Complex Molecular Systems, Eindhoven University of Technology, P.O. Box 513, Eindhoven, 5600 MB, The Netherlands.
Journal of the American Chemical Society
|January 23, 2023
概括
有机太阳能电池使用非富勒烯受体,具有强烈的近红外吸收. 这些材料在固体膜中形成极子,增强光吸收并提高光伏电池的效率.
科学领域:
- 材料科学
- 有机电子
- 太阳能发电
背景情况:
- 非富勒烯受体 (NFAs) 对于有机太阳能电池 (OSC) 是至关重要的.
- 在近红外 (NIR) 频谱中,NFAs具有强烈的吸收.
- 在固态阶段强烈的光物质相互作用会导致激子-极子的形成.
研究的目的:
- 在固相非富勒烯受体中研究极子形成.
- 分析极子对光吸收和光伏性能的影响.
- 用乙烯-乙烯核 (Y6型) 进行NFAs的表征.
主要方法:
- 多晶Y6型NFA薄膜的反射光谱.
- 对光谱特征进行分析以确定极子特征.
- 使用纯Y6型NFA的光伏电池的制造和效率测试.
主要成果:
- 在Y6型NFA膜的反射光谱中观察到明显的极子特征.
- 确定了与允许的分子转换相关的反射带的局部最小值.
- 已经证明,减少反射使光线更有效地进入,增加了外部量子效率.
结论:
- 在固相Y6型NFAs中证实了极子形成.
- 观察到的极子效应增强了有机太阳能电池的光收获.
- 这一发现为优化基于NFA的光伏设备提供了途径.
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