通过添加来提高Fe-N-C催化剂的氧气电催化活性
Yazhou Zhou1,2, Ruihu Lu3, Xiafang Tao1,2
1Max Planck Institute for Polymer Research, Mainz 55128, Germany.
Journal of the American Chemical Society
|February 6, 2023
概括
在铁--碳催化剂中的结合显著增强了氧的演化反应活性. 通过有效的双功能氧气电催化, 这一突破改善了可充电的空气电池.
科学领域:
- 电化学
- 材料科学
- 催化剂
背景情况:
- 用单原子铁 (Fe-N-C) 合的石墨碳材料是氧降解反应 (ORR) 的关键催化剂.
- 这些Fe-N-C材料在氧化演化反应 (OER) 中表现不佳,因为O-O合速度缓慢,限制了它们在可充电的空气电池中的使用.
研究的目的:
- 增强Fe-N-C催化剂的氧化演化反应 (OER) 活性.
- 为可充电的空气电池开发先进的双功能电催化剂.
主要方法:
- 将原子纳入Fe-N-C催化剂的第二个协调球,产生P/Fe-N-C材料.
- 在0.1M KOH中进行电化学表征.
- 第一个原则是密度函数理论计算.
主要成果:
- 这种P/Fe-N-C材料表现出极好的OER活性,在10 mA cm-2下具有304 mV的低超电位.
- 氧降解反应/氧演变反应 (ORR/OER) 的潜力间隙显著小,达到0.63V.
- 理论计算表明可以在FeN4位点平衡*OOH/*O吸附,从而提高催化活性.
- 可充电Zn-空气电池中的P/Fe-N-C阴极提供了269 mW cm-2的高峰功率密度.
结论:
- 将纳入第二个协调领域是促进Fe-N-C催化剂OER活动的有效策略.
- 作为可充电空气电池的最先进的双功能氧气电催化剂,P/Fe-N-C材料具有前景.
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