用于高温电容储能的梯形共聚物
Jie Chen1, Yao Zhou2, Xingyi Huang3
1Shanghai Key Laboratory of Electrical Insulation and Thermal Ageing, Department of Polymer Science and Engineering, Frontiers Science Center for Transformative Molecules, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai, China.
Nature
|March 1, 2023
概括
新的ladderphane共聚物为高温电容储能提供了卓越的性能. 这些材料具有显著较低的导电性和较高的导热性,克服了介电聚合物开发的关键挑战.
科学领域:
- 材料科学
- 聚合物化学
- 能量储存
背景情况:
- 用于高温电容储能的介电聚合物需要低电导率和高热导率.
- 对于当前的聚合物材料来说,同时实现这两种特性是一个重大挑战.
研究的目的:
- 开发具有增强高温电容储能性能的新型介电聚合物.
- 研究 ladderphane 共聚物的性能在苛刻的能量存储应用中.
主要方法:
- 阶梯共聚物的合成.
- 在高温和高电场下对电和热性能进行表征.
- 对电容器的能量密度和充放电效率进行评估.
主要成果:
- 在高电场和高温下,与现有聚合物相比,梯形共聚物具有数量级较低的电导率.
- 在200°C时实现了5.34 J cm-3的放电能量密度,并达到90%的充放电效率.
- 由于通过π-π堆叠自组装,表现出1.96 ±0.06 W m-1 K-1的内在导热率.
- 在高温下表现出卓越的循环稳定性和自愈能力.
结论:
- 对于在极端条件下运行的高能量密度聚合物电容,梯形共聚物是一种有前途的解决方案.
- 这些聚合物中低电导和高热导的独特组合克服了当前介电材料的关键限制.
- 自组装机制和自我修复特性进一步增强了它们用于先进的储能应用的潜力.
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