表面结构的拓变化,使使用过的离子电池阴极能够直接再生
Kai Jia1,2, Junxiong Wang1,2, Zhaofeng Zhuang1
1Tsinghua Shenzhen International Graduate School &Tsinghua-Berkeley Shenzhen Institute (TBSI), Tsinghua University, Shenzhen 518055, China.
Journal of the American Chemical Society
|March 6, 2023
概括
回收使用过的离子电池至关重要. 这项研究通过转换表面相来增强LIB阴极再生,以改善离子传输,提高性能.
科学领域:
- 材料科学
- 电化学
- 可持续能源
背景情况:
- 使用过的离子电池 (LIB) 带来了资源和环境挑战.
- 由于破坏Li+运输的表面相阻碍了LiNi0.5Co0.2Mn0.3O2 (NCM523) 阴极的直接回收.
- 这导致补充不足,再生阴极性能差.
研究的目的:
- 开发一种有效的回收NCM523阴极的方法.
- 为了克服表面岩盐/旋相所造成的+运输限制.
- 提高再生LIB阴极的容量和循环性能.
主要方法:
- 岩盐/螺旋阶段的拓变化为Ni0.5Co0.2Mn0.3(OH) 2.
- 随后的转换回到NCM523的阴极结构.
- 通过减少静电排斥的修改道促进+运输.
主要成果:
- 在低迁移障碍的情况下实现了快速的拓性化过程.
- 在再生过程中显著改善了+补充.
- 再生阴极的电化学性能与原始商业阴极相提并论.
- 已证明适用于各种已使用的NCM和LiCoO2阴极.
结论:
- 通过优化+运输通道,拟议的方法有效地再生了消耗的LIB阴极.
- 这种方法为提高LIB回收提供了一个新的视角.
- 该技术是多用途的,适用于不同的阴极化学.
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